Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ2N,N′)copper(II) dihydrate
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چکیده
منابع مشابه
Diacetatobis(propane-1,3-diamine)nickel(II) dihydrate
In the title complex, [Ni(CH(3)COO)(2)(C(3)H(10)N(2))(2)]·2H(2)O, the Ni(II) atom resides on a centre of symmetry and is in an octa-hedral coordination environment comprising four amino N atoms and two carboxyl-ate O atoms. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds produce R(2) (1)(6), R(2) (2)(12), R(3) (2)(8) and R(5) (5)(16) rings, which generate a two-dimensional polymeric network para...
متن کاملBis[tris(ethane-1,2-diamine)nickel(II)] octacyanidomolybdate(IV) dihydrate
The title complex, [Ni(II)(C(2)H(8)N(2))(3)](2)[Mo(IV)(CN)(8)]·2H(2)O, crystallized from a mixture of ethane-1,2-diamine (en), octa-cyano-molybdate(IV), [Mo(CN)(8)](4-), and the transition metal ion Ni(2+). In the crystal structure, the Mo polyhedron has a square-anti-prismatic shape, while the geometry around the Ni atom is distorted octa-hedral. The complex ions and water mol-ecules are linke...
متن کاملTris[tris(ethane-1,2-diamine)cobalt(II)] bis[octacyanidomolybdate(V)] dihydrate
In the title compound, [Co(II)(C(2)H(8)N(2))(3)](3)[Mo(V)(CN)(8)](2)·2H(2)O, N-H⋯N and N-H⋯O hydrogen-bonding inter-actions give rise to a three-dimensional network. In the crystal structure, each Mo polyhedron has a square-anti-prismatic shape, while the Co complexes show distorted octa-hedral geometry with an occupancy of 50%. One of the Co atoms resides on a crystallographic inversion centre.
متن کاملBis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ2 N,N′)copper(II) dihydrate
In the title compound, [Cu(C(3)H(10)N(2))(2)(C(6)H(6)NO(3)S)(2)]·2H(2)O, the Cu(II) atom lies on an inversion center and is hexa-coordinated by four N atoms from two 1,3-diamino-propane ligands and two O atoms from two 4-amino-benzene-sulfonate ligands in a trans arrangement, displaying a distorted and axially elongated octa-hedral coordination geometry, with the O atoms at the axial positions....
متن کامل[N,N,N′,N′-Tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-diamine]nickel(II) dinitrate dihydrate
In the title compound, [Ni(C(38)H(38)N(10))](NO(3))(2)·2H(2)O, the Ni(II) ion is located on a crystallographic twofold rotation axis and is in a distorted octa-hedral coordination environment. The crystal structure is stablized by inter-molecular N-H⋯O and C-H⋯O hydrogen bonds, and weak C-H⋯π inter-actions. The O atoms of the unique nitrate ion are disordered over two sites with occupancies of ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809049769